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Birch bark tar (sometimes referred to as birch bark pitch) is a substance that is synthesized by of tree bark.


Chemical composition
Birch bark tar is mainly composed of compounds of the lupane and family, which can be used as biomarkers to identify birch bark tar in the archaeological record. The most characteristic molecules are and , which are also present in birch bark.Hayek, E.W.H., Jordis, U., Moche, W., Sauter, F., 1989. A bicentennial of betulin. Phytochemistry. 28, 2229–2242.Hayek, E.W.H., Krenmayr, P., Lohninger, H., 1990. Identification of Archaeological and Recent Wood Tar Pitches Using Gas Chromatography/Mass Spectrometry and Pattern Recognition. Some of these molecules degrade into other lupane and oleanane skeleton triterpenes. The most commonly found additional molecules are lupenone, betulone, lupa-2,20(29)-dien-28-ol, lupa-2,20(29)-diene and allobetulin.Aveling, E., Heron, C., 1998. Identification of Birch Bark Tar at the Mesolithic Site of Star Carr. Ancient Biomolecules. 2.Regert, M., 2004. Investigating the history of prehistoric glues by gas chromatography-mass spectrometry. journal of separation science. 27, 244–254.Rageot, M., 2015. Les substances naturelles en Méditerranée nord-occidentale (VIe-Ie Millénaire BCE) : chimie et archéologie des matériaux exploités pour leurs propriétés adhésives et hydrophobes (Doctorat). Université Nice Sophia Antipolis.


Ancient and modern uses
Birch bark tar use as an began in the Middle . produced tar through dry distillation of as early as 200,000 years ago. A 2019 study demonstrated that birch bark tar production can be a simpler, more discoverable process by directly burning birch bark under overhanging stone surfaces in open-air conditions. However, at Königsaue (Germany), Neanderthals did not make tar with this method but rather employed a technically more demanding underground production method. A find from the Dutch North Sea and two tools from the Italian site Campitello show that Neanderthals used birch bark tar as a backing on small 'domestic' stone tools.

Birch bark tar also has been used as a , in dressing, and in medicine.

A piece of 5,000-year-old made from birch bark tar, and still bearing tooth imprints, was found in , Finland. Genetic material left in the gum enabled novel research to identify population movements, types of food consumed, and types of oral bacteria found on their teeth. Ancient gum DNA, Science, The New York Times, December 17, 2019

A different chewing gum sample, dated to 5,700 years old, was found in southern . A complete and oral was sequenced from chewed birch bark tar. Researchers identified that the individual who chewed the gum was a female who was closely related genetically to from mainland Europe.

on were fastened with birch bark tar, and rawhide lashing and birch bark tar were used to fix blades in the Mesolithic period.

Birch bark tar was more frequently discovered in archaeological contexts dating from the to the . For example, birch bark tar was identified to serve as an adhesive to repairBosquet, D., Regert, M., DUBOIS, N., Jadin, I., 2001. Identification de brai de bouleau sur quatre vases du site rubané de Fexhe-le-Haut-Clocher «Podrî l’Cortri». Premiers résultats.Urem-Kotsou, D., Mitkidou, S., Dimitrakoudi, E., Kokkinos, N., Ntinou, M., 2018. Following their tears: Production and use of plant exudates in the Neolithic of North Aegean and the Balkans. Quaternary International. 496, 68–79.Urem-Kotsou, D., Stern, B., Heron, C., Kotsakis, K., 2002. Birch-bark tar at Neolithic Makriyalos, Greece. Antiquity. 76, 962–967.Rageot, M., Lepère, C., Henry, A., Binder, D., Davtian, G., Filippi, J.-J., Fernandez, X., Guilaine, J., Jallet, F., Radi, G., Thirault, E., Terradas, X., Regert, M., 2021. Management systems of adhesive materials throughout the Neolithic in the North-West Mediterranean. Journal of Archaeological Science. 126, 105309. and decorate/paint ceramic vessels,Morandi, L.F., Porta, S.N., Ribechini, E., 2018. Evidence for Birch Bark Tar Use as an Adhesive and Decorative Element in Early Iron Age Central Italy: Technological and Socio-Economic Implications. Archaeometry. 60, 1077–1087. as a sealing/waterproofing agent.Hayek, E.W.H., Krenmayr, P., Lohninger, H., 1990. Identification of Archaeological and Recent Wood Tar Pitches Using Gas Chromatography/Mass Spectrometry and Pattern Recognition. Regert, M., Vacher, S., Moulherat, C., Decavallas, O., 2003. Adhesive Production and Pottery Function During the Iron Age at the Site of Grand Aunay (Sarthe, France)*. Archaeometry. 45, 101–120. A well-known example of birch bark tar during the copper age is Ötzi’s hafted arrow points and copper axe.Sauter, F., Ulrich, J., Graf, A., Werther, W., Varmuza, K., 2000. Studies in organic archaeometry I: identification of the prehistoric adhesive used by "Tyrolean Icemen" to fix his weapons. Arkivoc. V, 735–747. Multiple discoveries show that birch bark tar was also used to assemble metal artefacts, such as pendants and other ornaments, on both a functional and decorative level.Regert, M., Rolando, C., 2002. Identification of Archaeological Adhesives Using Direct Inlet Electron Ionization Mass Spectrometry. Analytical chemistry. 74, 965–75.Courel, B., Schaeffer, P., Féliu, C., Thomas, Y., Adam, P., 2018. Birch bark tar and jewellery: The case study of a necklace from the Iron Age (Eckwersheim, NE France). Journal of Archaeological Science: Reports. 20, 72–79. During the , birch bark tar is mostly replaced by wood tar,Balsan, L., 1951. L’industrie de la résine dans les Causses et son extension dans l’empire romain. Gallia. 9, 53–55.Trintignac, A., 2003. La production de poix dans la cité des gabales (Lozère) à l’époque gallo-romaine. RAP. n°1/2, 239–248. but birch bark tar is still used, for example, to decorate hinges and other bone objects.Regert, M., Rodet-Belarbi, I., Mazuy, A., Dantec, G., Dessì, R.M., Henry, A., Rageot, M., Briz, S., 2019. Birch bark tar in the Roman world: the persistence of an ancient craft tradition. Antiquity. 93.

is a water-resistant leather, oiled with birch bark oil after tanning. This leather was a major from seventeenth- and eighteenth-century Russia, as the availability of birch bark oil limited its geographical production. The oil impregnation also deterred insect attack and gave a distinctive and pleasant aroma that was seen as a mark of quality in leather.

Birch bark tar is also one of the components of Vishnevsky liniment.

Birch bark tar is an effective of . The repellent effect lasts about two weeks. The repellent effect of birch bark tar oil mixed with and applied to a fence can last up to several months.

Birch bark tar oil has strong antiseptic properties,Wanamaker, L, "Birch Tar Oil A Powerful Antiseptic", OtzisPouch, 2020-04-01 owing to a large amount of phenol derivatives and terpenoid derivatives.

Birch bark tar oil was used in the eighteenth century alongside civet and and many other aromatic substances to scent the fine Spanish leather Peau d'Espagne. At the turn of the twentieth century, birch bark tar had become a specialty fragrance material in as a base note to impart a leathery, smoky note in fragrances, especially from the leather and tobacco genre, and to a lesser extent in , especially Cuir de Russie perfumes and fragrance bases, typically together with castoreum and isobutyl quinoline. It is used as an ingredient in some soaps, i.e. the scent of soap, though other tars (i.e. from pine, coal) with an equally and smoky odour are more commonly used in soaps as a medicating agent.


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